Planarization is achieved by the use of a rigid polishing pad that provides mechanical abrasion. Chemicalmechanical polishing cmp is often associated with chemicalmechanical planarization which is a polishing process assisted by chemical reactions to remove surface materials. Selective chemical mechanical polishing using surfactants. Chemical mechanical polishing cmp uses a combination of chemical and mechanical effects, and thus higher removal rate with damagefree surface could be achieved.
We applied our original chemical mechanical polishing cmp simulator based on the tightbinding quantum chemical molecular dynamics tbqcmd method to clarify the atomistic mechanism of cmp processes on a cu111 surface polished with a sio2 abrasive grain in aqueous h2o2. Chemical mechanical polishing of silicon carbide the high temperature integrated electronics and sensors hties team at the nasa lewis research center is developing silicon carbide sic as an enabling electronic technology for many aerospace applications. The user should be aware that the nature of the chemical polishing process demands care and personal protection at all times. Theory and experiment for several decades, chemical mechanical polishing cmp has been the most widely used planarization method in integrated circuits manufacturing.
Tana aschool of mechanical and aerospace engineering, nanyang technological university, 50 nanyang avenue, singapore 639798, republic of singapore bsingapore institute of manufacturing technology, 71 nanyang drive, singapore 638075, republic of singapore. For several decades, chemical mechanical polishing cmp has been the most widely used planarization method in integrated circuits manufacturing. The chemicalmechanical polishing of sapphire with 0001, 1012, 1120 crystal orientations at use of aqueous suspension of silica as a polishing means has been studied. A method of fabricating a polishing layer of a polishing pad includes successively depositing a plurality of layers with a 3d printer, each layer of the plurality of polishing layers deposited by ejecting a pad material precursor from a nozzle and solidifying the pad material precursor to form a solidified pad material. Pdf investigating slurry transport beneath a wafer. Apply to chemical engineer, car wash attendant, supervisor and more. Abstract in order to better understand the role of the fluid behavior in chemical mechanical planarization, we measured slurry transport beneath a glass wafer. Material removal mechanism in chemical mechanical polishing. Atomistic insights into cu chemical mechanical polishing. Chemical mechanical polishing of gallium nitride with. Damascene process and chemical mechanical planarization. Within wafer nonuniformity wiwnu, which significantly affects the yield of chip products, is mainly caused by nonuniform chemical. Cmp chemical mechanical planarization solutions for the integration of highk metal gate technologies.
In principle, cmp is a process of smoothing and planing surfaces with the combination of chemical and mechanical forces. The kemcol 15 machine is ideal for chemical mechanical polishing cmp, and cerium oxide based polishing applications. Surfactant mediated passivation to achieve chemical mechanical polishing selectivity by kyoungho bu may 2007 chair. Cmp mechanisms can offer guidance to the control and optimization of the polishing processes. Chemical mechanical polishing cmp is the planarization method that has. This document is intended to introduce the techniques of chemical mechanical polishing cmp to the new user so that they may be better prepared to integrate cmp into their process flow. New to cmp cmp chemical mechanical planarization customers just starting in cmp or considering implementing the process find substantial benefits from utilizing entrepix cmp fast forward services. In order to enable highk metal gate technology, new chemical mechanical planarization steps or slurries are needed to meet the stringent planarity or. It is thus widely adopted for planarizing interlevel dielectric silicon dioxide layers. Chemical mechanical polishing device market pdf by.
Atomistic mechanisms of chemical mechanical polishing of a. Our team of industryexperienced cmp professionals brings its knowledge to bear on every customer interaction to complete yield analysis on first production wafers and support ramp through. Chemical mechanical polishing cmp1214 is the effective method to realize high removal and highquality subsurface and surface through chemical and mechanical interaction. Microscratch induced by chemical mechanical polishing cmp is a chronic problem to device yieldkilling and its criticality becomes more important in sub14nm device manufacturing. Chemical mechanical polishing cmp has been widely used in polishing glass and ceramic surfaces as well as in planarizing semiconductor wafers. Theory and experiment for several decades, chemical mechanical polishing cmp has been the most widely.
Chemical mechanical polishing or planarization is a process of smoothing surfaces with the. Moreover, cmp is a critical process for fabricating the cu damascene patterns, lowk dielectrics. Preferably, the chemical mechanical polishing pad 10 includes a pressure sensitive platen adhesive 70 applied to the bottom surface 27 of the subpad 25. Chemical mechanical polishing cmp is an indispensable technique in the microelectronics industry to achieve planarization and patterning of metal and dielectric layers. To do this, chipmakers use a process called chemicalmechanical planarization, or cmp, for short. Snider department of electrical engineering, university of notre dame, notre dame, indiana 46556. The polishing experiments were carried out using a cmp tool umt tribolab, san jose, ca. A model of chemical mechanical polishing mrs online. The report on global chemical mechanical polishing device market is a professional report which provides thorough knowledge along with complete information pertaining to the chemical.
Cmp is a standard manufacturing process practiced at the semiconductor industry to fabricate integrated circuits and memory disks. Chemical mechanical polishing system operation manual. The chemical mechanical polishing cmp process has emerged as a critical technique to smooth surface topography. Pdf stress distribution in chemical mechanical polishing. B s pabla3 1 research scholar, mechanical department,national institute of technical teachers training research chandigarh india. Whether this entails planarizing exotic new materials or providing proven solutions for todays copper, oxide, tungsten, or sti challenges across an array of technology. Compared with the commonly used spherical silica sol, the nonspherical silica sol can remove holes on the surface of zirconia ceramics to achieve nanometerscale surface roughness. Cmp is a standard manufacturing process practiced at the semiconductor industry. To clarify the chemical mechanical polishing cmp mechanism of cu in aqueous hydrogen peroxide and glycine, we developed a reaxff reactive force field to describe the interaction between cu, slurry h2o, h2o2, and glycine, and the silica abrasive. The polishing process consists of using small abrasive particles to remove a thin layer of material which. The effect of mechanical and chemical polishing techniques. Nsfsrc engineering research center for environmentally benign semiconductor manufacturing philipossian 6 schematic diagram of postcmp scrubbing wafer pva brush.
Pdf chemical mechanical polishing of cubic silicon. Additionally, new materials such as cu and w, introduced in ulsi fabrication, also require extensive use of the cmp process to form inlaid interconnect structures. Chemical mechanical polishing cmp of fused silica fs. Surface roughness was measured using surface analyzing instrument in. Ebaras applications engineering groups in japan and the u. This paper provides a tribochemical study of the selective layer surface by chemical mechanical planarization cmp. Intrinsic component wear component overall fit depth of contact data3 0 201 1040 30 20 10 0 10 20 30 a low b medium c high in steady state polishing, surface structure is determined by balance between restorative effect of conditioning and destructive effect. Us6083089a method and apparatus for chemical mechanical. Chemical mechanical polishingplanarization cmp slurries are abrasive materials, also called noncrystalline inorganic oxides, which are dispersed in. Mechanical grinding alone may theoretically achieve planarization but the surface damage is. Compared with other planarization techniques, the chemical mechanical polishing cmp process produces excellent local and global planarization at low cost. Chemical mechanical planarization for microelectronics applications. In an effort to improve the silicon carbide sic substrate surface, a new electrochemical mechanical polishing ecmp technique was developed.
The substrate is forcibly pressed against the polishing pad with pneumatic or hydraulic pressure applied to the backside of the substrate. Ceria abrasive has been used to polishing of silicate and silica material1517 due to its appropriate hardness and high removal. More preferably, the chemical mechanical polishing pad 10 can be affixed to the platen using at least one of a pressure sensitive adhesive and vacuum. Cmp involves pouring a mixture of chemicals and sand moreorless on a spinning disc of special sandpaper and polishing away. In this study, chemical mechanical polishing of zirconia ceramics was first carried out using novel nonspherical silica abrasives. Based on this force field, we used molecular dynamics simulations to illustrate the chemistry at the cusilica abrasive interface and cu atom.
A model of chemical mechanical polishing volume 6 ed paul. The model results agree with the experimental removalrate decay results. Effect of polishing pad material properties on chemical mechanical polishing cmp processes volume 337 rajeev bajaj, mukesh desai, rahul jairath, matthew stell, robert tolles. Chemical mechanical polishing or planarization is a process of smoothing surfaces with the combination of chemical and mechanical forces. Global chemical mechanical polishing cmp diamond pad. We quantified the slurry transport using residence time distribution techniques and two. Planarization of wafer edge profile in chemical mechanical polishing. Pdf chemical mechanical glass polishing with cerium. A novel method and apparatus for uniformly polishing thin films formed on a semiconductor substrate. We reveal that the oxidation of the cu111 surface mechanically induced at the friction interface is a key process in cmp.
Controlled chemical mechanical polishing of polysilicon and silicon dioxide for singleelectron device vishwanath joshi,a alexei o. Effect of selected physicochemical characteristics on polishing efficiency article pdf available june 2016 with 2,230 reads how we. Chemical mechanical polishing cmp is a material removal process that was used to polish and planarize glass sheets and lenses for decades before the semiconductor industry applied it to the production of integrated circuit ic devices. A substrate is placed face down on a moving polishing pad so that the thin film to be polished is placed in direct contact with the moving polishing pad. Cmp chemical mechanical polishing steag mecapol 460. Materials science and engineering chemical mechanical polishing cmp is an indispensable technique in the microelectronics industry to achieve planarization and patterning of metal and dielectric layers. The final polishing results are affected by many factors related to the carrier structure, the polishing pad, the slurry, and the process parameters. Pdf polishing, the most expensive machining processes, in terms time and labor costs depending on the required surface finish, optic size.
Chemical mechanical glass polishing with cerium oxide. Damascene process steps damascene is an additive process firstly, the dielectric is deposited secondly, the dielectric is etched according to the defined photoresist pattern, and then barrier layer is deposited thirdly, copper is deposited optimum way of copper deposition is electroplating copper electrodeposition is a two step process. Chemical mechanical polishing cmp is often associated with chemical mechanical planarization which is a polishing process assisted by chemical reactions to remove surface materials. Chemicalmechanical impact of nanoparticles and ph effect. Dornfeld abstract the abrasion mechanism in solidsolid contact mode of thechemical mechanical polishingcmp processis investigated in detail. Chemical mechanical polishing systems ebara technologies.
Electrochemical mechanical polishing of silicon carbide. Chemical mechanical polishing of cubic silicon carbide films grown on si100 wafers. Pdf abrasive for chemical mechanical polishing researchgate. At one time, the cmp process was viewed as too dirty to use for the highlyprecise business of semiconductor manufacturing. This analytical solution is compared with experimental data from journal of electronic materials, 25, no. Chemical processes in the chemical mechanical polishing of copper. This is the process where the top surface of a wafer is polished with a slurry containing an abrasive grit, suspended within reactive chemical agents. The machine is based on the popular kemet 15 lapping and polishing machine, but incorporates stainless steel elements in place of painted components for. Chemical mechanical polishing of polymeric materials for mems applications z. Analysis of slurry flow in chemicalmechanical polishing. Pad conditioning effects in chemical mechanical polishing. The mechanism is different from grinding, as chemical mechanical polishing cmp works in the atomic regime.
It can, in a way, be thought of as a hybrid of chemical etching and free abrasive polishing. Pad height pdf asperity aspect ratio dh30 20 10 0 10 f r equenc y a. Mechanics, mechanisms and modeling of the chemical mechanical polishing process kyungyoon noh, jiunyu lai, nannaji saka, and junghoon chun abstract the chemical mechanical polishing cmp process is now widely employed in the in. Pdf on oct 24, 2018, hong jin kim and others published abrasive for chemical mechanical polishing find, read and cite all the research. Chemical mechanical polishing of polymeric materials for. Chemical polishing slurry is set to boom in 2020 and.
The chemical mechanical synergy plays a key role in the. Nanoscale surface of zro2 ceramics achieved efficiently. Chemical mechanical polishing process carrier retaining ring slurry polish platen pad pad conditioner downforce. Analytical solution for polishrate decay in chemical. Controlled chemical mechanical polishing of polysilicon. Effect of polishing pad material properties on chemical. Chemical mechanical polishing is more commonly known as cmp polishing. What is chemical mechanical polishing or cmp polishing. Us20283700a1 printed chemical mechanical polishing. Mechanics, mechanisms and modeling of the chemical. The sixty ac specimens received mechanical and chemical polishing in the same manner.
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